Preliminary occurrence studies of antibiotic residues in Hong Kong and Pearl River Delta

An improved liquid chromatography–tandem mass spectrometry (LC-MS/MS) method was developed and validated to investigate the occurrence of selected antibiotic residues in Hong Kong and Pearl River Delta. LC and MS parameters were optimized to produce the maximum analytical responses for each compound. The established method targeted five groups of antibiotics, namely, macrolides, sulfonamides, tetracyclines, quinolones, and amphenicols. The method was validated for three types of environmental water matrices, namely, reservoir, river, and estuarine waters. Low detection limits of 0.17–0.18 ng/L for macrolides, 0.22–0.34 ng/L for quinolones, 0.67–1.65 ng/L for tetracyclines, and 0.27–0.56 ng/L for sulfonamides were obtained. No apparent interferences were observed in the chromatograms of all antibiotics groups. The developed method was preliminarily used to analyze water samples collected from Yuen Long River in New Territories, Hong Kong and four sites along the Pearl River Delta. Results showed that high level of tetracycline was found among the groups tested in the local river samples. In Pearl River Delta, we identified significant levels of erythromycin, roxithromycin, and sulfadiazine in Shenzhen Reservoir.     

Risk assessment of PCDD/Fs levels in human tissues related to major food items based on chemical analyses and micro-EROD assay

Nine groups of food items (freshwater fish, marine fish, pork, chicken, chicken eggs, leafy, non-leafy vegetables, rice and flour) and three types of human samples (human milk, maternal serum and cord serum) were collected for the analysis of PCDD/Fs. Results of chemical analysis revealed PCDD/Fs concentrations (pg g^− 1 fat) in the following ascending order: pork (0.289 pg g^− 1 fat), grass carp (Ctenopharyngodon idellus) (freshwater fish) (0.407), golden thread (Nemipterus virgatus) (marine fish) (0.511), chicken (0.529), mandarin fish (Siniperca kneri) (marine fish) (0.535), chicken egg (0.552), and snubnose pompano (Trachinotus blochii) (marine fish) (1.219). The results of micro-EROD assay showed relatively higher PCDD/Fs levels in fish (2.65 pg g^− 1 fat) when compared with pork (0.47), eggs (0.33), chicken (0.13), flour (0.07), vegetables (0.05 pg g^− 1 wet wt) and rice (0.05). The estimated average daily intake of PCDD/Fs of 3.51 pg EROD-TEQ/kg bw/day was within the range of WHO Tolerable Daily Intake (1–4 pg WHO-TEQ/kg bw/day) and was higher than the Provisional Tolerable Daily Intake (PMTL) (70 pg for dioxins and dioxin-like PCBs) recommended by the Joint FAO/WHO Expert Committee on Food Additives (JECFA) [Joint FAO/WHO Expert Committee on Food Additives (JECFA), Summary and conclusions of the fifty-seventh meeting, JECFA, 2001.]. Nevertheless, the current findings were significantly lower than the TDI (14 pg WHO-TEQ/kg/bw/day) recommended by the Scientific Committee on Food of the Europe Commission [European Scientific Committee on Food (EU SCF), Opinions on the SCF on the risk assessment of dioxins and dioxin-like PCBs in food, 2000.]. However, it should be noted that micro-EROD assay overestimates the PCDD/Fs levels by 2 to 7 folds which may also amplify the PCDD/Fs levels accordingly. Although the levels of PCDD/Fs obtained from micro-EROD assay were much higher than those obtained by chemical analysis by 2 to 7 folds, it provides a cost-effective and rapid screening of dioxin levels in food and human samples.     

VOCs 组分监测数据在改进香港PATH 模型中的作用

 利用香港2 个监测站的VOCs 组分监测数据对香港PATH 模型进行了验证分析.结果明,PATH 模型在模拟VOCs 组分浓度上存在较大的误差.实际观测的VOCs 组分AOD、OLE、TOL 和XYL 浓度是模型模拟的2~3 倍;而模型模拟的PAR 和ETH 浓度是实际观测的 2~4倍.这些误差可能是由于当前使用的VOCs 排放清单低估了实际的VOCs 排放量,以及在估算来自不同排放源的排放量及组分分布上有较大的不确定性.使用高质量的VOCs 组分监测数据验证PATH 模型有助于指导改进VOCs 排放清单和理解复杂的光化学烟雾污染问题,从而改进和提高PATH 模型.     

Impacts of environmental factors on urban heating

This study investigated the impact of important environmental variables (i.e.,wind speed,solar radiation and cloud cover) on urban heating.Meteorological parameters for fifteen years (from 1990 to 2005),collected at a well developed and densely populated commercial area (Tsim Sha Tsui,Hong Kong),were analyzed in details.Urban heat island intensity (UHII),a well known indicator of urban heating,has been determined as the spatially averaged air-temperature difference between Tsim Sha Tsui and Ta Kwu Ling (a thinly populated rural area with lush vegetation).Results showed that the UHII and cloud cover have increased by around 9.3% and 4%,respectively,whereas the wind speed and solar radiation have decreased by around 24% and 8.5%,respectively.The month of December experienced the highest UHII (10.2°C) but the lowest wind speed (2.6 m/sec) and cloud cover (3.8 oktas).Conversely,the month of April observed the highest increases in the UHII (over 100%) and the highest decreases in wind speed (over 40 %) over fifteen years.Notably,the increases in the UHII and reductions in the wind speed were the highest during the night-time and early morning.Conversely,the intensity of solar radiation reduced while the intensity of urban cool island (UCII) increased during solar noon-time.Results demonstrated strong negative correlation between the UHII and wind speed (coefficient of determination,R2=0.8) but no negative correlation between UCII and solar radiation attenuation.A possible negative correlation between UHII and cloud cover was investigated but could not be substantiated.     

An overview of emissions trading and its prospects in Hong Kong

With the approval of the Chinese central government, the Government of the Hong Kong Special Administrative Region (HKSAR) decided to participate in a regional emissions trading (ET) pilot scheme in the Pearl River Delta (PRD) region. This scheme, instead of aiming to curb global warming, is geared mostly toward reducing air pollutant (that is, SO₂, NO_x, RSP, and VOCs) emissions by 20–55% by 2010, thus improving air quality in the region. Both the HKSAR and the Guangdong Provincial Governments will impose emission caps on their respective power plants in the region and allocate emissions credits to them. This study explores the background of this regional ET scheme and correlates it with the emissions reduction scenario to provide more details for assessing its applicability to Hong Kong and Guangdong Province. Although practicing ET in the PRD region presents many challenges, establishing an appropriate ET scheme is of paramount importance for Hong Kong, as well as other cities in the PRD region, to achieve a sustainable air quality.     

整全,互动和可持续的EIA：香港上水屠宰场的例案研究

以香港上水屠宰场的ＥＩＡ为例，阐述了ＥＩＡ过程须结合“清洁工艺”、“环境管理系统”、“持续生的本底监测”和“开放的公众咨询”四个重要单元，互动灵活，以增强环保效益、省时及经济。传统的ＥＩＡ较为被动，如果项目“倡议人”缺乏环保意识，就会妨碍了它的实质功能。通行的末期性公众咨询，很容易激发冲突，与西方冗长的公众参与同样妨碍进度。文章探讨互动式ＥＩＡ的优点，论证它对改善环评工序和可持续发展的重要性。